
For peer-to-peer assistance, visit Outlook Forums or subscribe to the Outlook-Users mailing list.
Subscribe to Exchange Messaging Outlook, a weekly newsletter about Outlook and Exchange Server
A reader asks: "I have about six different eMail addresses for different items of personal and work life... I wish I could make a 'toolbar' with the different accounts and actually 'click' on the account I want to make a new eMail from. I don't know how many times I've sent personal mail using my [default] work account... you know?"
You can create templates with the account selected and hyperlink them to a
toolbar. Note that if you make a new profile and the account names change
even slightly, you'll need to resave the template for that account.
http://www.slipstick.com/outlook/mool_acct.htm
has screenshots and detailed instructions.
Updated Friday January 15 2010